Ultimate Spider-Man, Vol. 1 #114 (2007)

Death of A Goblin, Part 3
Peter's first priority is to ensure the safety of MJ and his Aunt May, which is tricky due to the fact that May is on a date with Miles Warren. Still, he manages it, and then heads to Osborn's home to follow any lead he can get. Once there, he finds Electro, and the two have a brawl that spills out into the streets, where they are both captured by S.H.I.E.L.D.
Release Date: 2007