Superior Spider-Man, Vol. 1 #24 (2013)

Darkest Hours, Part 3
DARKEST HOURS Part 3 of 4: 'Complications' - The birth of a new Goblin! The return of Cardiac! MJ's greatest fear! - And the one question everyone will be asking: 'Who is THE SUPERIOR VENOM?!' - Good luck, Superior Spider-Man! You're gonna need it!
Release Date: 2013