Ultimate Spider-Man, Vol. 1 #42 (2003)

Temptations
Spider-Man tracks down Geldoff and tries to talk him into using his powers more responsibly. He takes a moment to interrupt a robbery, and has it under control when Geldoff blows up a car to try and help. Spider-Man loses his temper, and the two are about to fight when three of the X-Men arrive to talk to Geldoff about what he can do.
Release Date: 2003